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The Payenia region of Argentina (34.5–38°S) is a large Pliocene‐Quaternary volcanic province of basaltic compositions in the Andean Cordillera foothills representing the northernmost extent of back‐arc volcanism in the Andean Southern Volcanic Zone (SVZ). Although the chemical diversity of the Payenia basalts has been characterized previously, the processes and sources responsible for such variation remain controversial. Here, we report new whole‐rock major and trace element concentrations, Sr‐, Nd‐, Hf‐, and Pb‐isotope ratios and high‐precision olivine oxygen‐isotope ratios in a suite of 35 alkaline basalts from Payenia. These lavas have major and trace elements that define a compositional range from arc‐influenced to intraplate signature. Variable crustal contamination and/or recent slab‐derived inputs inadequately account for elemental and isotopic systematics and spatial compositional variations of Payenia lavas. We present a simple forward model indicating that early metasomatism and subsequent melting of the metasomatized subcontinental lithospheric mantle (SCLM) has significantly contributed to the Payenia lava compositional range. Isotopic ingrowth calculations of radiogenic Sr, Nd, Hf, and Pb suggest that the SCLM metasomatism occurred at 50–150 Ma, consistent with the timing of the breakup of Gondwana and the development of the proto‐Pacific Andean arc. Variations in δ¹⁸O_olivinevalues from modeled melts indicate that the metasomatism and melting within the SCLM can fractionate oxygen isotopes even when the metasomatizing melt has MORB‐like δ¹⁸O values, providing a different explanation for the low‐δ¹⁸O signatures observed in continental arc settings.

New trace element abundances and isotope compositions for more than 100 mid‐ocean ridge basalts from 5.5°N to 19°N on the East Pacific Rise show step function variations in isotopic composition along the ridge axis that coincide with ridge discontinuities. Transform faults, overlapping spreading centers, and devals (deviation from axial linearity) mark the separation of individual clusters of distinct isotopic composition and trace element ratios that indicate source variations. This correlated chemical clustering and morphological segmentation indicates that source composition and segmentation can be closely related even on a fine scale. Substantial chemical variations within a segment are related to source composition. This suggests that even within segments the magma transport is mainly vertical, and there is limited along‐ridge transport, and there is little evidence for magma chambers that are well mixed along strike. Trace element concentrations show good correlations with isotopic compositions on a segment scale but less so on a regional scale. The trace element and isotopic variability along the northern East Pacific Rise can be explained by three mantle components: a depleted peridotite endmember, an enriched peridotite endmember, and a recycled gabbro‐like component. The gabbroic component has an isotopic signature indicating an ancient origin. The high‐resolution sampling indicates that within a segment the chemical variability is largely binary but that the endmembers of the binary mixing change from segment to segment. The endmembers of the binary variation within a segment are a combination of three of the endmembers.